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AARBOR COLORANTS CORPORATION


Technical Bulletin AArbor Monopigment Concentrate
A/TA/06-2009 Flush for Plastics.

Phthalocyanine Pigment Flushes for Plastics masterbatches.
AArbor’s mono-pigment concentrated Flush for Plastics.
  AArbor Code PE8801D, PE8800D & PE5200D is the trade name for phthalo blue and green flushes in high quality polyethylene wax. These are based on copper phthalocyanine pigments.
Plastic flushes are an established product for high quality masterbatches. For film and fibres.
  AArbor flushes are similar to many multinational brands. These may differ from one another in composition, hue, chroma and color strength.
PRODUCT COLOR INDEX CHEMICAL NATURE SIMILAR PRODUCT
Manufacturer         Product
AArbor Blue PE8801D PB 15:1 Stabilised alpha modification
with PE wax
Avecia                    Ploymon ED
Clariant                  Remafin AE
AArbor Blue PE8800D PB 15:3 Beta modification with PE wax  
AArbor Green PE5200D
 
PG 7 Chlorinated cpc with PE wax  

PROPERTIES

The properties listed are determined according to following test conditions.

Physical properties :-
a) Bulk density : Similar to DIN 53194
b) Size : Sieving method
c) Pigment content : Ashing method.
2. Application properties :-

The flush is converted into standard masterbatch at 10% pigment level in LD before checking the following properties.
a) Coloristic properties : Checked in LD moulding chip.
b) Heat stability : This is checked in HDPE after keeping in injection barrel for 5 minutes at the stated temperature.
c) Film test : The film is taken out at 25 + 5  oC   thickness at 4% pigment level 60 cm length x 10 cm width film is checked for dispersion (after converting flush into masterbatch).
d) Migration : A 2 x 2 cm piece is kept in contact with TiO2 pigment white piece at 80oC / 2 Hrs. under 100 gm/cm2 load. The staining is checked after removal.
e) Light fastness : This data related to occasional testing on representative batches.
Heavy metals : As per AP 89 (1) regulation.

APPLICATION IN MASTERBATCHES

ADVANTAGES OF PLASTIC FLUSH FOR MASTERBATCHES –

  • Most suitable for film and fibre
  • Standardised colour strength.
  • Excellent dispersion characteristics.
  • High colour value.
  • Agglomerate free.
  • Non dusting.
  • Reduction in losses.
  • Increased productivity.
  • High pigmentation easily possible.
  • Ease of mixing.
  • Higher filler loading.

PLASTIC FLUSHES

Various pigments have different dispersion characteristics. This depends upon
  • Type of pigment
  • Nature of surface treatment
  • Polymer characteristics
  • Dispersion additives
  • Dispersion machinery

Among the pigments, high performance polycyclic pigments like phthalocyanines, quinacridones etc. are hard to disperse. Their dispersion hardness is high. The pigments for plastics need to be finer. As they become finer, the dispersion related problems increase.

The result is agglomeration, difficulty to achieve high pigment loading, lower colour strength, high energy input to achieve dispersion, necessity to use costly dispersion machinery, lower productivity and need strict control on process parameters.

This has severe effects in coloration of thin films and fine denier fibre production.

The films have specks, on continuity and may tear off. The film with such defects can not be used in many applications. In fibre production, the agglomerated particles cause frequent choke up of spinnerates. This results in loss of productivity, more downtime and inferior quality of fibres. The properties of fibres are affected by oversized particles.

With the best of pigment powders the particle size achieved after dispersion could be 5 – 10 mµ.using best dispersion machineries. Thus, pigment powders have limitations to achieve fine dispersion, lower pigment loading is another limitation.

FLUSHES –

Flushing is an established technique of transferring the pigment from aqueous phase into the polymer of application. This began in ink industry wherein this is a standard technique.

Since the pigment is transferred from presscake stage into polymer, the particle size is maintained between 2 – 5 mµ The agglomeration and hardening during conventional drying is avoided. The pigment primary particles are coated with polyethylene wax which prevents the pigment from reagglomeration. Since the pigment is already fully dispersed in wax which is compatible with the polymer, final masterbatch with any pigment level ( below that of flush) is possible using even low shear dispersion machines.

The result is agglomerate free, high color strength stable dispersion which needs much less energy input.

The productivity increases. Handling of pigment powders result in dusty atmosphere. Flushes are easier to handle and they can be metered into machine in a better manner than powders, maintaining clean environment.

There is another advantage of maintaining lesser inventory of colours. Using selected primary flushes, a wide range of shades can be manufactured in a faster way.

AARBOR FLUSHES FOR PLASTICS –

They are made from plastic grade pigment press cake manufactured in our modern plant. AArbor offers 50% pigment content in high grade polyethylene wax. The wax allows the flush to be used in Polyolefines and PVC. with which it is compatible.

The flushes are controlled for various quality parameters listed earlier.

 

MASTERBATCH MANUFACTURING


Formulation I –
Blue Shade for thin film
  A% B%
Pigment blue --- 25
PE wax --- 10
LLDPE 50 65
PE8800D (50%) 50 ---
  100 100
Machine Single screw extruder Twin screw extruder
Pre-mixing Not required Required
Colour strength 110% 100%
Color Brighter ----
Film Clear, better agglomerates observed
Dispersion Easy Difficult
Formulation II –
Green shade for moulding.
  A B
Pigment green --- 8
PE wax --- 2
Calcium carbonate 23 20
LLDPE 61 70
PE5200D (50%) 16 ---
  100 100
Pre-mixing Not required required
Machine Single screw extruder Kneader followed by
Color strength 108% 100%
Colour Brighter ---

SPECIFICATION

Product Pigment Content PE Wax Size mm Bulk Density Heat Stability Migration Light fastness
FT   RT
Film test 25 mµ Purity requirements (Heavy metals) AP 89(1) & EN 71 Melt temp. 106-108 oC
AArbor Blue PE8801D 50 50 2 – 3   280 oC 5 8      8 To pass to pass
AArbor Blue PE8800D 50 50 2 – 3   280 oC 5 8      8 To pass to pass
AArbor Green PE5200D 50 50 2 – 3   300 oC 5 8      8 To pass to pass


Compatibility :

AArbor flushes are compatible with Low Density Polypropylene, High Density Polypropylene, PP (film, fibre, sheeting, containers, injection moulding).

AArbor flushes can also be used for coloration of rigid & flexible PVC (film, sheet, moulding etc.)

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